Quantum escape kinetics over a fluctuating barrier

The escape rate of a particle over a fluctuating barrier in a double well potential exhibits resonance at an optimum value of correlation time of fluctuation. This has been shown to be important in several variants of kinetic model of chemical reactions . We extend the analysis of this phenomenon of resonant activation to quantum domain to show how quantization significantly enhances resonant activation at low temperature due to tunneling.

Pulak Kumar Ghosh, Debashis Barik, Bidhan Chandra Bag, Deb Shankar Ray · 2006