# Kinetic control for planar oxidation of MoS$\_2$

Source: [Kinetic control for planar oxidation of MoS$\_2$](<https://www.sota2.com/research/paper/68fa430f1e209131ce9072c4>)

Collection index: [llms.txt](<https://www.sota2.com/research/llms.txt>)

Data updated: 2025-10-25T04:07:07.356Z

Authors: Kate Reidy, Wouter Mortelmans, Seong Soon Jo, Aubrey Penn, Baoming Wang, Alexandre Foucher, Frances M. Ross, R. Jaramillo

Published: 2022-11-30T07:03:05.000Z

## Abstract

Layered transition metal dichalcogenide (TMD) semiconductors oxidize readily in a variety of conditions, and a thorough understanding of this oxide formation is required for the advancement of TMD-based microelectronics. Here, we combine scanning transmission electron microscopy (STEM) with spectroscopic ellipsometry (SE) to investigate oxide formation at the atomic scale of the most widely-studied TMD, MoS$\_2$. We find that aggressive thermal oxidation results in $\\alpha$-phase plate-like crystalline MoO$\_3$ with sharp interfaces, voids, and a textured alignment with the underlying MoS$\_2$. Experiments with remote substrates and patterned MoS$\_2$ prove that thermal oxidation proceeds via vapor-phase mass transport and redeposition - a challenge to forming thin, conformal planar oxide films. We accelerate the kinetics of oxidation relative to the kinetics of mass transport using a non-thermal oxygen plasma process, to form a smooth and conformal amorphous oxide. The resulting amorphous MoO$\_3$ films can be grown several nanometers thick, and we calibrate the oxidation rate for varying plasma processing conditions. Our results illustrate how TMD semiconductor oxidation differs significantly from oxidation of legacy semiconductors, most notably silicon, and provide quantitative guidance for managing both the atomic scale structure and thin film morphology of oxides in the design and processing of MoS$\_2$ semiconductor devices.

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## Original sources and implementation

[Original paper](<https://arxiv.org/abs/2211.16789>)

[PDF](<https://arxiv.org/pdf/2211.16789.pdf>)