# Specific features of the kinetics of singlet fission in organic semiconductors. The effect of kinetic curves crossing

Source: [Specific features of the kinetics of singlet fission in organic semiconductors. The effect of kinetic curves crossing](<https://www.sota2.com/research/paper/68fa38491e209131ce8b93a1>)

Collection index: [llms.txt](<https://www.sota2.com/research/llms.txt>)

Data updated: 2025-10-27T03:53:38.277Z

Authors: A. I. Shushin

Published: 2018-08-31T19:20:12.000Z

## Abstract

Experimental investigations of magnetic field dependent kinetics of singlet fission (SF)processes in some organic semiconductors \[i.e. splitting of excited singlet (S\_1) state into a triplet exciton pair\] have revealed the important specific feature of obtained kinetic curves, associated with decaying intensities I(t) of fluorescence from S\_1-state. Kinetic curves, measured in different magnetic fields, are found to cross each other. We show that this kinetic curves crossing (KCC) effect is a general feature of geminate condensed phase reactions, resulting from simple characteristic properties of kinetic schemes of processes. Specific features of the KCC-effect are analyzed in detail with some models of SF-processes.

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## Original sources and implementation

[Original paper](<https://arxiv.org/abs/1809.00031>)

[PDF](<https://arxiv.org/pdf/1809.00031.pdf>)
