# Lost chapter of Physical Chemistry means convergence between Fisher Kolmogorov equation and tunnel effect Source: [Lost chapter of Physical Chemistry means convergence between Fisher Kolmogorov equation and tunnel effect]() Collection index: [llms.txt]() Data updated: 2025-10-24T20:42:39.894Z Authors: Jimenez Edward, Mosquera Hector, Cortez Marco, Esteban Jimenez, Carlos E. Ayala, Lopez Gustavo, Stahl Ullrich Published: 2016-09-27T19:24:24.000Z ## Abstract In this work we show that the dynamics of chemical reactions of order zero, one and two have a representation through logistics probability. This probability is robust, stable and complies systemically with the differential equation of Fisher Kolmogorov (F K). It is robust, because in theorem 1 and theorem 3 differential equations of diffusion and heat transfer are obtained, where the temperature plays a key role. Also, the Eikonal equation of wave mechanics allows us to construct the heat equation. In Lemma 2, Fick diffusion equation is demonstrated. It is stable, because probability convergence when t converge infinitum, gives us new ways to analyze the kinetics of a reaction integrally, in Corollary 5. Finally, the theoretically and experimentally obtained algorithms and results support the convergence in probability of the quantum tunnel effect and chemical reactions for: hydrogen production at ultra low temperature and catalytic cracking of asphalt at high temperature. ## Recorded benchmark results A research result applies to its stated dataset, split, metric and evaluation configuration. Compare like-for-like settings, preserve the metric's unit and direction, and distinguish paper-reported results from independent reproduction. The best result recorded here is not a claim of exhaustive, current global coverage. ## Original sources and implementation [Original paper]() [PDF]()