# On the Adam-Gibbs-Wolynes scenario for the viscosity increase in glasses

Source: [On the Adam-Gibbs-Wolynes scenario for the viscosity increase in glasses](<https://www.sota2.com/research/paper/68fa343b1e209131ce896f98>)

Collection index: [llms.txt](<https://www.sota2.com/research/llms.txt>)

Data updated: 2025-10-24T20:31:20.587Z

Authors: J.-P. Bouchaud, G. Biroli

Published: 2004-06-14T15:22:05.000Z

## Abstract

We reformulate the interpretation of the mean-field glass transition scenario for finite dimensional systems, proposed by Wolynes and collaborators.  This allows us to establish clearly a temperature dependent length xi\* above which the mean-field glass transition picture has to be modified. We argue in favor of the mosaic state introduced by Wolynes and collaborators, which leads to the Adam-Gibbs relation between the viscosity and configurational entropy of glass forming liquids.  Our argument is a mixture of thermodynamics and kinetics, partly inspired by the Random Energy  Model: small clusters of particles are thermodynamically frozen in low energy states, whereas large clusters are kinetically frozen by large activation energies. The relevant relaxation time is that of the smallest \`liquid' clusters. Some physical consequences are discussed.

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## Original sources and implementation

[Original paper](<https://arxiv.org/abs/cond-mat/0406317>)

[PDF](<https://arxiv.org/pdf/cond-mat/0406317.pdf>)
