# Kinetics of the elementary act of electrochemical reactions at the semiconductor--electrolyte solution interface

Source: [Kinetics of the elementary act of electrochemical reactions at the semiconductor--electrolyte solution interface](<https://www.sota2.com/research/paper/68fa2e491e209131ce86134b>)

Collection index: [llms.txt](<https://www.sota2.com/research/llms.txt>)

Data updated: 2025-10-24T16:48:53.275Z

Authors: Sergii Kovalenko, Veniamin Soloviev

Published: 2013-11-04T10:37:23.000Z

## Abstract

In the framework of the quantum-mechanical theory of elementary act of non-adiabatic electrochemical reactions, it is carried out the calculation of the discharge current of ions at the semiconductor--electrolyte solution interface using the model of isotropic spherically symmetric band. It is shown that our results generalize the well-known formulae for the current density obtained by Dogonadze, Kuznetsov, and Chizmadzhev \[R.R. Dogonadze, A.M. Kuznetsov, and Yu.A. Chizmadzhev, The kinetics of some heterogeneous reactions at semiconductor--electrolyte interface, Zhur. Fiz. Khim. 38 (1964) 1195--1202\]. The average densities of states in the valence band and the conduction band of the semiconductor electrode in the heterogeneous charge transfer are found.

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## Original sources and implementation

[Original paper](<https://arxiv.org/abs/1311.0639>)

[PDF](<https://arxiv.org/pdf/1311.0639.pdf>)