# Recrystallization of glass: homogeneous vs. heterogeneous nucleation in La(0.5)Ca(0.5)MnO3

Source: [Recrystallization of glass: homogeneous vs. heterogeneous nucleation in La(0.5)Ca(0.5)MnO3](<https://www.sota2.com/research/paper/68fa211e7a2b558e2933540d>)

Collection index: [llms.txt](<https://www.sota2.com/research/llms.txt>)

Data updated: 2025-10-28T13:52:12.017Z

Authors: A. Banerjee, Kranti Kumar, P. Chaddah

Published: 2007-11-15T14:01:05.000Z

## Abstract

We probe through magnetization and resistivity measurements a kinetically arrested glass-like but long-range ordered magnetic state. The transformation kinetics of the magnetic field-temperature induced broad first-order transition from ferromagnetic-metallic (FMM) to antiferromagnetic-insulating (AFI) state gets hindered at low temperature in a La(0.5)Ca(0.5)MnO3 sample. A fraction of high-temperature FMM phase persists to the lowest temperature, albeit as a non-ergodic state. We present a phenomenology for this glass-like but long-range order FMM phase which devitrifies on heating and converts to equilibrium AFI phase. The residual kinetically arrested FMM phase can be \`recrystallized' to AFI state by annealing and more efficiently by successive annealing, presumably by heterogeneous nucleation. This glass-like state shows a stimulating feature that when the fraction of glass is larger the \`recrystallization' is easier.

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## Original sources and implementation

[Original paper](<https://arxiv.org/abs/0711.2347>)

[PDF](<https://arxiv.org/pdf/0711.2347.pdf>)
